跳转至内容
Merck

117722

Sigma-Aldrich

1-金刚烷甲酰氯

95%

别名:

1-Adamantanecarboxylic acid chloride, 1-Chlorocarbonyladamantane

登录查看公司和协议定价


About This Item

经验公式(希尔记法):
C11H15ClO
CAS号:
分子量:
198.69
Beilstein:
389960
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

solid

bp

135-136 °C/10 mmHg (lit.)

mp

49-51 °C (lit.)

官能基

acyl chloride

SMILES 字串

ClC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11-

InChI 密鑰

MIBQYWIOHFTKHD-KJZNFTALSA-N

正在寻找类似产品? 访问 产品对比指南

一般說明

1-金刚烷羰基氯与异丙基亚磷酸三乙胺反应生成混合酸酐,这是一种用于氢-膦酸盐 DNA 合成的有效封端试剂 。它是金属铟存在下苯甲醚 Friedel–Crafts 酰化反应的良好底物

應用

1-金刚烷羰基氯被用于制备高效的胺修饰的寡脱氧核苷酸,用于制备 DNA 微阵列

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本?

如果您需要特殊版本,可通过批号或批次号查找具体证书。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

其他客户在看

Novel activating and capping reagents for improved hydrogen-phosphonate DNA synthesis.
Andrus A, et al.
Tetrahedron Letters, 29(8), 861-864 (1988)
Nagendra Kumar Kamisetty et al.
Analytical and bioanalytical chemistry, 387(6), 2027-2035 (2007-01-24)
Amine-modified oligodeoxynucleotides (AMO) are commonly used probe oligodeoxynucleotides for DNA microarray preparation. Two methods are currently used for AMO preparation--use of amine phosphoramidites protected by acid-labile monomethoxytrityl (MMT) groups or alkali-labile trifluoroacetyl (TFA) groups. Because conventional AMO preparation procedures have
Anna K Blakney et al.
Biomacromolecules, 21(6), 2482-2492 (2020-04-07)
Messenger RNA (mRNA) is a promising platform for both vaccines and therapeutics, and self-amplifying RNA (saRNA) is particularly advantageous, as it enables higher protein expression and dose minimization. Here, we present a delivery platform for targeted delivery of saRNA using
Evgenii S Mozhaitsev et al.
Anti-cancer agents in medicinal chemistry, 19(4), 463-472 (2018-12-14)
The DNA repair enzyme tyrosyl-DNA-phosphodiesterase 1 (TDP1) is a current inhibition target to improve the efficacy of cancer chemotherapy. Previous studies showed that compounds combining adamantane and monoterpenoid fragments are active against TDP1 enzyme. This investigation is focused on the
Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal.
Jang DO, et al.
Tetrahedron Letters, 47(34), 6063-6066 (2006)

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门