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Merck

11268

Sigma-Aldrich

四乙基碳酸氢铵

≥95.0% (T)

别名:

Tetraethylammonium hydrogen carbonate

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About This Item

线性分子式:
(CH3CH2)4N(HCO3)
CAS号:
分子量:
191.27
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥95.0% (T)

形狀

solid

SMILES 字串

OC([O-])=O.CC[N+](CC)(CC)CC

InChI

1S/C8H20N.CH2O3/c1-5-9(6-2,7-3)8-4;2-1(3)4/h5-8H2,1-4H3;(H2,2,3,4)/q+1;/p-1

InChI 密鑰

XUBMPLUQNSSFHO-UHFFFAOYSA-M

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應用

四乙基碳酸氢铵:
  • 用于由胺合成氨基甲酸酯。
  • 作为沉淀剂,通过共沉淀法合成 Cu/ZnO 催化剂。
  • 作为 [18] 放射性氟化中传统相转移系统的替代,用于防止微反应器堵塞。
  • 用于在恶唑烷-2,4-二酮的合成中,促进在 α-位上带有离去基团的二级甲酰胺的羧化。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Tetraethylammonium hydrogen carbonate in organic synthesis: Synthesis of oxazolidine-2, 4-diones.
Cesa S, et al.
Tetrahedron, 55(1), 193-200 (1999)
Ying Fu et al.
Journal of proteomics, 130, 108-119 (2015-09-19)
Powdery mildew (Pm), caused by Blumeria graminis f. sp. tritici (Bgt), is one of the most important crop diseases, causing severe economic losses to wheat production worldwide. However, there are few reports about the proteomic response to Bgt infection in
A convenient method for the synthesis of carbamate esters from amines and tetraethylammonium hydrogen carbonate.
Inesi A, et al.
The Journal of Organic Chemistry, 63(4), 1337-1338 (1998)
Evaluation of tetraethylammonium bicarbonate as a phase-transfer agent in the formation of [18F] fluoroarenes.
Reed CD, et al.
Journal of Fluorine Chemistry, 143(4), 231-237 (2012)
Monica M Schroll et al.
Journal of the American Society for Mass Spectrometry, 29(10), 2012-2022 (2018-07-19)
Short-term glucose starvation prior to chemotherapy has the potential to preferentially weaken cancer cells, making them more likely to succumb to treatment, while protecting normal cells. In this study, we used 3D cell cultures of colorectal cancer and assessed the

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