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CF0027

Sigma-Aldrich

Phenylsulfanyltetrafluoropropionic acid Cs salt

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About This Item

Linear Formula:
C9H5F4O2SCs
MDL number:
UNSPSC Code:
12352101

form

solid

reaction suitability

reaction type: C-C Bond Formation

Application

Phenylsulfanyltetrafluoropropionic acid Cs salt is as a less hygroscopic, crystalline source of phenylsulfanyltetrafluoropropionic acid. A phenylsulfanyltetrafluoroethyl moiety incorporated in the substrate can be treated with tributyltin hydride and generate the corresponding fluoroalkyl radical. If the substrate lacks any olefins, it can be reduced to tetrafluoroethyl group whereas if the substrate contains an olefin in the correct spatial orientation, it can lead to an intramolecular cyclization affording tetrafluorinated cyclic structures.

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Legal Information

Product of CF Plus Chemicals.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

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