930105

S-(4-nitrophenyl) methanethioate

≥95%

• Synonym(s): p-NO₂-phenyl thioCORMate, p-NO₂-phenyl thioformate
• Empirical Formula (Hill Notation): C₇H₅NO₃S
• CAS Number: 27064-04-6
• Molecular Weight: 183.18
• MDL number: MFCD34704553
• UNSPSC Code: 12352101
• NACRES: NA.06

Properties

• Quality Level: 100
• Assay: ≥95%
• form: powder
• reaction suitability: reaction type: C-C Bond Formation
• functional group: nitro; thioether
• storage temp.: 2-8°C
• SMILES string: [H]C(SC1=CC=C([N+]([O-])=O)C=C1)=O
• InChI: 1S/C7H5NO3S/c9-5-12-7-3-1-6(2-4-7)8(10)11/h1-5H
• InChI key: WWSZWQFPBOUBQE-UHFFFAOYSA-N

Description

Application

S-(4-nitrophenyl) methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO rapidly for faster reactions that require instantaneous on-demand generation of CO. using only a simple amine to activate it.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable