930059

S-Phenyl methanethioate

• Synonym(s): Phenyl thioCORMate, Phenyl thioformate
• Empirical Formula (Hill Notation): C₇H₆OS
• CAS Number: 27064-03-5
• Molecular Weight: 138.19
• MDL number: MFCD32756471
• UNSPSC Code: 12352101
• NACRES: NA.06

Properties

• form: liquid
• Quality Level: 100
• refractive index: n/D 1.586
• density: 1.134 g/mL
• storage temp.: −20°C
• SMILES string: [H]C(SC1=CC=CC=C1)=O

Description

Application

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 221.0 °F
• Flash Point(C): 105 °C