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422843

Sigma-Aldrich

Potassium trifluoromethanesulfonate

98%

Synonym(s):

Potassium triflate, Trifluoromethanesulfonic acid potassium salt

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About This Item

Linear Formula:
CF3SO3K
CAS Number:
Molecular Weight:
188.17
Beilstein:
3727495
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

powder

SMILES string

[K+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.K/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

GLGXXYFYZWQGEL-UHFFFAOYSA-M

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General description

Potassium trifluoromethanesulfonate (KOTf, potassium triflate) is the potassium salt of trifluoromethanesulphonic acid. It has been prepared by neutralizing a warm aqueous solution of trifluoromethanesulphonic acid with potassium carbonate. The structure of siloxane–poly(oxyethylene) hybrids doped with potassium triflate has been investigated.

Application

Potassium trifluoromethanesulfonate (potassium triflate) is suitable as a reagent in the synthesis of guanine-quadruplex hybrid materials by the self-assembly of a guanine-siloxane monomer.
It may be used in the following studies:
  • As a template source for constructing the heterotopic isothiosemicarbazide-based macrocyclic ligand.
  • As a supporting electrolyte in the electrochemical study of evidence for gold anion in ethylenediamine.
  • As a reagent in the synthesis of imidazolium salt, 3-methyl-1-(3R,3aR,6S,6aR)-[6-(benzyloxy)-hexahydrofuro[3,2-b]furan-3-yl]imidazolium trifluoromethanesulfonate.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Local and nanoscopic structure of potassium triflate-doped siloxane-polyoxyethylene ormolytes.
Chaker JA, et al.
Journal of Non-Crystalline Solids, 352(32), 3457-3462 (2006)
Sol-gel selection of hybrid G-quadruplex architectures from dynamic supramolecular guanosine libraries.
Mihai S, et al.
Journal of Materials Chemistry, 20(42), 9443-9448 (2010)
Evidence for the gold anion in ethylenediamine.
Jagannathan R, et al.
Inorganic Chemistry, 24(1), 113-114 (1985)
Gregory D Bowden et al.
Scientific reports, 9(1), 11370-11370 (2019-08-08)
Recent advancements in 18F radiochemistry, such as the advent of copper-mediated radiofluorination (CMRF) chemistry, have provided unprecedented access to novel chemically diverse PET probes; however, these multicomponent reactions have come with a new set of complex optimization problems. Design of
Synthesis of novel chiral imidazolium-based ionic liquids derived from isosorbide and their applications in asymmetric aza Diels-Alder reaction.
Van Buu ON, et al.
Tetrahedron, 65(11), 2260-2265 (2009)

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