252387
Pentafluoropropionic anhydride
99%
Synonym(s):
PFPA, Perfluoropropionic anhydride
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About This Item
Linear Formula:
(CF3CF2CO)2O
CAS Number:
Molecular Weight:
310.05
Beilstein:
1806446
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
99%
form
liquid
bp
69-70 °C/735 mmHg (lit.)
density
1.571 g/mL at 25 °C (lit.)
functional group
anhydride
SMILES string
FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F
InChI
1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16
InChI key
XETRHNFRKCNWAJ-UHFFFAOYSA-N
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Application
Pentafluoropropionic anhydride was used:
- in preparation of halogenated derivatives of phenolic acids, required for determination of some biologically important acids in cerebrospinal fluid
- as derivatization reagent in detection of 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain by GC-multiple ion detection
- in simultaneous determination of the major metabolites of dopamine in rat striatum by gas-liquid chromatography
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Y S Oh-Shin et al.
Journal of chromatography. A, 769(2), 285-291 (1997-05-09)
A rapid and simple gas chromatographic method for the simultaneous determination of malathion, parathion, fenitrothion, diazinon and carbaryl in drinking water is presented. A fused-silica SE-54 column was used for the separation of the insecticides and was split into two
I Jakasa et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 811(2), 177-182 (2004-11-04)
We developed a sensitive method for determination of polyethylene glycols (PEGs) of different molecular weight (MW) in the human stratum corneum (SC) obtained by tape stripping. The analysis is based on derivatization with pentafluoropropionic anhydride (PFPA) and gas chromatography-electron capture
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