Degradation of optical and surface properties of resin-based composites with distinct nanoparticle sizes but equivalent surface area.

To determine the optical and surface properties of model resin-based composites made with distinct nanoparticle sizes but equalized surface area, among them, before and after ageing. Model resin-based composites based on BisGMA/TEGDMA (50:50mol%) were loaded with three different fumed silica filler content (7nm/examethyldisilazane, 12nm/octylsilane, and 16nm/dimethylchlorosilane), but with equivalent surface area (BET method). The optical and surface properties of the disk-shaped specimens were measured in 24h after photoactivation (baseline) and repeated after water storage (90days at 37°C), and after abrasion (20,000 cycles of brushing). CIELAB individual parameters, color difference (ΔE* CIE L* and TP were not affected by ageing in any group. CIE a* was increased and CIE b* decreased for the 12nm and 16nm groups and did not show any difference for the 7nm group. After ageing, the lowest ΔE* The optical properties of the tested materials were not dependent of the fillers' surface area, while the surface properties were. Several factors influence the ageing resistance of the resin-based composites, including the surface area of the fillers and the amount and coupling treatment of them. The improvement of the material's physical stability could avoid the premature replacement of dental restorations.