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Merck

Enol tosylates as viable partners in Pd-catalyzed cross-coupling reactions.

The Journal of organic chemistry (2005-11-19)
Dietrich Steinhuebel, Jenny M Baxter, Michael Palucki, Ian W Davies
ABSTRAKT

[reaction: see text] Herein we demonstrate functionalized enol tosylates to be robust substrates that undergo Suzuki-Miyaura, Sonogashira, and Stille cross-coupling reactions to provide stereodefined trisubstituted unsaturated esters.

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Methylboronic acid, 97%