Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.

Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.

Chemical communications (Cambridge, England) (2012-07-28)

Teng Zhang, Feijie Song, Wenbin Lin

ABSTRAKT

Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.

MATERIAŁY

Numer produktu

Marka

Opis produktu

236071

Sigma-Aldrich

N,N′-Bis(salicylidene)ethylenediamine, 98%