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Tributylphosphine-catalyzed cycloaddition of aziridines with carbon disulfide and isothiocyanate.

The Journal of organic chemistry (2008-10-24)
Jing-Yu Wu, Zhi-Bin Luo, Li-Xin Dai, Xue-Long Hou
ABSTRAKT

Aziridines underwent cyclization reaction with carbon disulfide and isothiocyanate in the presence of organophosphine to afford thiazolidinone derivatives in good to high yields. The mechanistic study revealed that organophosphine serves as a catalyst in the reaction.

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Sigma-Aldrich
Tributylphosphine, mixture of isomers, 97%
Sigma-Aldrich
Tributylphosphine, ≥93.5% (Tri-N-butylphosphine, GC)
Sigma-Aldrich
Tri-n-butylphosphine, 97%
Sigma-Aldrich
Tributylphosphine solution, 200 mM (in N-methyl-2-pyrrolidinone), liquid
Sigma-Aldrich
Tri-n-butylphosphine, 99%