P63808
2,6-Pyridinedicarboxylic acid
99%
Synonym(s):
DPA, DPAc, Dipicolinic acid
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Assay
99%
form
crystals
mp
248-250 °C (dec.) (lit.)
SMILES string
OC(=O)c1cccc(n1)C(O)=O
InChI
1S/C7H5NO4/c9-6(10)4-2-1-3-5(8-4)7(11)12/h1-3H,(H,9,10)(H,11,12)
InChI key
WJJMNDUMQPNECX-UHFFFAOYSA-N
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Application
Used to prepare dipicolinato ligated lanthanide and transition metal complexes.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
370.4 °F - closed cup
Flash Point(C)
188 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Bulletin of the Chemical Society of Japan, 64, 3659-3659 (1991)
Nature chemistry, 9(9), 856-861 (2017-08-25)
Electron transfer in mixed-valent transition-metal complexes, clusters and materials is ubiquitous in both natural and synthetic systems. The degree to which intervalence charge transfer (IVCT) occurs, dependent on the degree of delocalization, places these within class II or III of
J. Ind. Chem. Soc., 71, 9-9 (1994)
Scientific reports, 8(1), 2315-2315 (2018-02-06)
The new type of catalysts designed for the olefin derivatives polymerization has been synthetized. The novel catalysts are chromium(III) salt type complexes composed of both organic cation and anion, i.e. [Cr(dipic)2][Cr(bipy)(dipic)H2O]∙2H2O and [Cr(dipic)2]Hdmbipy∙2.5 H2O. The compositions of these complexes have
Bioorganic & medicinal chemistry letters, 18(2), 460-463 (2007-12-14)
Dihydrodipicolinate synthase (DHDPS) is a key enzyme in lysine biosynthesis and a potential antibiotic target. The enzyme catalyses the condensation of (S)-aspartate semi-aldehyde (ASA) and pyruvate to form dihydrodipicolinate. Constrained diketopimelic acid derivatives have been designed as mimics of the
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