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Key Documents

76063

Sigma-Aldrich

Palladium hydroxide on activated charcoal

greener alternative

moistened with water, 10-20% Pd basis (based on dry substance)

Synonym(s):

Pd(OH)2/C, Pearlman’s catalysts

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About This Item

MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

lumps

quality

moistened with water

contains

~50% water as stabilizer

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

10-20% Pd (based on dry substance)

greener alternative category

SMILES string

O[Pd]O

InChI

1S/2H2O.Pd/h2*1H2;/q;;+2/p-2

InChI key

NXJCBFBQEVOTOW-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.
Hydrogenation catalyst

Pictograms

Environment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Jung, M. E.; Choi, Y. M.
The Journal of Organic Chemistry, 56, 6729-6729 (1991)
Prugh, J. D.; Rooney, C. S. et al.
Tetrahedron Letters, 26, 2947-2947 (1985)
Zhao, S.; Freeman, J. P.; Szmuszkovicz, J.
The Journal of Organic Chemistry, 57, 4051-4051 (1992)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

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