680982

Cyclopropylzinc bromide solution

0.5 M in THF

• Synonym(s): Bromocyclopropylzinc, Cyclopropane, zinc complex, Cyclopropylzinc(II) bromide
• Empirical Formula (Hill Notation): C₃H₅BrZn
• CAS Number: 126403-68-7
• Molecular Weight: 186.37
• MDL number: MFCD08741505
• UNSPSC Code: 12352103
• PubChem Substance ID: 329760740
• NACRES: NA.22

Properties

• form: liquid
• Quality Level: 100
• concentration: 0.5 M in THF
• density: 0.969 g/mL at 25 °C; 0.969 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Br[Zn]C1CC1; Br[Zn]C1CC1
• InChI: 1S/C3H5.BrH.Zn/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1; 1S/C3H5.BrH.Zn/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
• InChI key: DUXRKEPSNWXJGV-UHFFFAOYSA-M; DUXRKEPSNWXJGV-UHFFFAOYSA-M

Description

Application

Active nucleophile in Pd-catalyzed cross-coupling of heteroaryl halides.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H302,H314,H335,H351
• Precautionary Statements: P201 - P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014,EUH018,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 1.4 °F - closed cup
• Flash Point(C): -17 °C - closed cup