51974
Nonafluoro-1-butanesulfonyl chloride
≥98.0% ((GC))
Synonym(s):
Perfluoro-1-butanesulfonyl chloride
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About This Item
Empirical Formula (Hill Notation):
C4ClF9O2S
CAS Number:
Molecular Weight:
318.55
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥98.0% ((GC))
SMILES string
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)S(Cl)(=O)=O
InChI
1S/C4ClF9O2S/c5-17(15,16)4(13,14)2(8,9)1(6,7)3(10,11)12
InChI key
IRFCLLARAUQTNK-UHFFFAOYSA-N
Other Notes
Reagent for fluoro-tagging of nucleophiles
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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C.W. Lindsley et al.
Tetrahedron Letters, 43, 4225-4225 (2002)
Graphitic carbon nitride polymer as a recyclable photoredox catalyst for fluoroalkylation of arenes.
Moritz Baar et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(2), 526-530 (2014-11-22)
Heterogeneous catalysis for trifluoromethylations and perfluoroalkylations has been performed. Through the usage of cheap, metal-free and recyclable mesoporous graphitic carbon nitride (mpg-CN) it was possible to fluoroalkylate various arenes by the reductive activation of sulfonyl chlorides with visible light. Thus
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