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417696

Sigma-Aldrich

Zinc bis[bis(trimethylsilyl)amide]

greener alternative

97%

Synonym(s):

Bis[1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]zinc, Bis[bis(trimethylsilyl)amido]zinc, Zinc bis(hexamethyldisilazide, 1,1,1,3,3,3-Hexamethyldisilazane zinc salt

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About This Item

Linear Formula:
[[(CH3)3Si]2N]2Zn
CAS Number:
Molecular Weight:
386.16
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

liquid

reaction suitability

core: zinc
reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

12.5 °C (lit.)

density

0.957 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

C[Si](C)(C)N([Zn]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/2C6H18NSi2.Zn/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2

InChI key

ZCCUYQBZUVUONI-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application


  • Cooperative effects of Schiff base binuclear zinc complexes on the synthesis of aliphatic and semi-aromatic polyesters.: This study explores the cooperative effects of binuclear zinc complexes in the synthesis of various polyesters, highlighting the potential of zinc bis[bis(trimethylsilyl)amide] in enhancing polymerization efficiency and selectivity (Santulli et al., 2023).

  • Synthesis, solution dynamics and chemical vapour deposition of heteroleptic zinc complexes via ethyl and amide zinc thioureides.: The authors discuss the synthesis and dynamics of zinc complexes for chemical vapor deposition, emphasizing the role of zinc bis[bis(trimethylsilyl)amide] as a precursor in developing high-purity metalorganic films (Bhide et al., 2021).

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B - Water-react 2

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

105.8 °F - closed cup

Flash Point(C)

41 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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