109223
1-Bromoadamantane
99%
Synonym(s):
1-Adamantyl bromide
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About This Item
Empirical Formula (Hill Notation):
C10H15Br
CAS Number:
Molecular Weight:
215.13
Beilstein:
1098857
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
mp
116-118 °C (lit.)
SMILES string
BrC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C10H15Br/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-
InChI key
VQHPRVYDKRESCL-CHIWXEEVSA-N
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General description
1-Bromoadamantane forms inclusion complexes with α-, β-, and γ-cyclodextrins. It causes the alkylation of Co(II) complexes of β-diketones.
Application
1-Bromoadamantane was used in the synthesis of a new organic–organic nanoscale composite thin-film dielectric.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Jitendra N Tiwari et al.
ChemSusChem, 3(9), 1051-1056 (2010-07-14)
A new organic-organic nanoscale composite thin-film (NCTF) dielectric has been synthesized by solution deposition of 1-bromoadamantane and triblock copolymer (Pluronic P123, BASF, EO20-PO70-EO20), in which the precursor solution has been achieved with organic additives. We have used a sol-gel process
Alkylation of ?-diketones through their co (II), co (III) and zn (II) complexes. 1-Bromoadamantane as alkylating agent.
Gonzalez A, et al.
Tetrahedron Letters, 26(31), 3735-3738 (1985)
P. M. Ivanov et al.
The Journal of organic chemistry, 61(20), 7012-7017 (1996-10-04)
The inclusion complexes between the most commonly used cyclodextrins (alpha-, beta-, and gamma-CD) and 1-bromoadamantane were prepared and studied experimentally by NMR methods and by molecular dynamics simulations (AMBER force field) with solvation. The NMR results suggest host/guest ratios of
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