900152
2-[[(2-Carboxyethyl)sulfanylthiocarbonyl]-sulfanyl]propanoic acid
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About This Item
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General description
- A stable, trithiocarbonate chain transfer agent (CTA), also referred to as a RAFT agent, which can control chain growth in free radical polymerization producing polymers with well-defined molecular weights and low polydispersities.
- 2-(2-Carboxyethylsulfanylthiocarbonylsulfanyl)propionic acid may be used to control homo- and co-polymerization of acrylic acid, acrylates, acrylamides, styrenes, methacrylates, and methacrylamides. It is soluble in aqueous and organic media (amphiphilic).
Caution
Storage conditions: Room temperature, protect from light.
Legal Information
Sold for research purposes only: See sigma-aldrich.com/raftlicense. Patents: WO98/01478, WO99/311444.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Synthesis and Evaluation of New Dicarboxylic Acid Functional Trithiocarbonates: RAFT Synthesis of Telechelic Poly(n-butyl acrylate)s.
Macromolecules, 38, 9518-9525 (2005)
Scale-up of the Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization Using Continuous Flow Processing.
Processes, 2, 58-70 (2014)
Synthesis of Dual-Functional Poly(6-azidohexylmethacrylate) Brushes by a RAFT Agent Carrying Carboxylic Acid End Groups.
Journal of Polymer Science Part A: Polymer Chemistry, 53, 1696-1706 (2015)
RAFT Inverse Miniemulsion Polymerization of Acrylic Acid and Sodium Acrylate.
Macromolecular Reaction Engineering, 5, 163-169 (2011)
Substituent Effects on Trithiocarbonates-Mediated Polymerization of Styrene.
Journal of Applied Polymer Science, 111, 2011-2017 (2009)
Artículos
The supply of low cost, high purity and effective Reversible addition−fragmentation chain-transfer (RAFT) Agents is the essential element in the industrial implementation of RAFT polymerization technology.
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