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Key Documents

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236233

Sigma-Aldrich

N-Methylaniline

≥99%

Sinónimos:

Monomethylaniline

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About This Item

Fórmula lineal:
C6H5NHCH3
Número de CAS:
100-61-8
Peso molecular:
107.15
Beilstein/REAXYS Number:
741982
EC Number:
202-870-9
MDL number:
MFCD00008283
UNSPSC Code:
12352100
PubChem Substance ID:
24854143
NACRES:
NA.22

Quality Level

100

assay

≥99%

form

liquid

refractive index

n20/D 1.571 (lit.)

bp

196 °C (lit.)

mp

−57 °C (lit.)

solubility

water: slightly soluble 30 g/L
alcohol: soluble(lit.)
diethyl ether: soluble(lit.)

density

0.989 g/mL at 25 °C (lit.)

SMILES string

CNc1ccccc1

InChI

1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3

InChI key

AFBPFSWMIHJQDM-UHFFFAOYSA-N

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Categorías relacionadas

General description

Chemical oxidation of N-methylaniline with dichromate (oxidant) has been studied by Raman spectroscopy.

Application

N-Methylaniline (NMA) was used in the preparation of self-assembled poly(N-methylaniline)-lignosulfonate (PNMA-LS) composite spheres with reactive silver-ion adsorbability. NMA was also used in electrodeposition of poly(N-methylaniline) (PNMA) coatings on a steel disc electrode using potentiodynamic, potentiostatic and galvanostatic techniques.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - STOT RE 2 Oral

Storage Class

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Qiu-Feng Lü et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(33), 10935-10944 (2013-07-03)
Self-assembled poly(N-methylaniline)-lignosulfonate (PNMA-LS) composite spheres with reactive silver-ion adsorbability were prepared from N-methylaniline by using lignosulfonate (LS) as a dispersant. The results show that the PNMA-LS composite consisted of spheres with good size distribution and an average diameter of 1.03-1.27
Electropolymerization of poly (N-methylaniline) on mild steel: Synthesis, characterization and corrosion protection.
Yag?an A, et al.
Journal of Electroanalytical Chemistry, 578(2), 231-238 (2005)
V Arjunan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 72(2), 436-444 (2008-12-17)
The Fourier transform infrared (FTIR) and FT-Raman spectra of 2-chloro-4-methylaniline and 2-chloro-6-methylaniline have been measured in the range 4000-400 and 4000-100cm(-1), respectively. Utilising the observed FTIR and FT-Raman data, a complete vibrational assignment and analysis of the fundamental modes of
Dongmei Li et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 291-297 (2008-12-18)
The mechanism of N-dealkylation of N-cyclopropyl-N-methylaniline () catalyzed by cytochrome P450 (P450) was investigated using density functional theory. This reaction involves two steps. The first one is a Calpha-H hydroxylation on the N-substituent to form a carbinolaniline complex, and the
S Ramalingam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(1), 84-92 (2010-03-26)
The FTIR and FTRaman spectra of 2-bromo-4-methyl aniline (2-B-4-MA) molecule have been recorded using Brucker IFS 66V spectrometer in the range of 4000-100 cm(-1). The molecular geometry and vibrational frequencies in the ground state are calculated using the Hartree-Fock (HF)
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