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101990

Sigma-Aldrich

4,4′-Dibromooctafluorobiphenyl

99%

Synonym(s):

1-Bromo-4-(4-bromo-2,3,5,6-tetrafluorophenyl)-2,3,5,6-tetrafluorobenzene

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About This Item

Linear Formula:
BrC6F4C6F4Br
CAS Number:
10386-84-2
Molecular Weight:
455.92
EC Number:
233-847-1
MDL number:
MFCD00000310
UNSPSC Code:
12352100
PubChem Substance ID:
24846559
NACRES:
NA.22

Assay

99%

form

solid

mp

113-115 °C (lit.)

functional group

bromo

SMILES string

Fc1c(F)c(c(F)c(F)c1Br)-c2c(F)c(F)c(Br)c(F)c2F

InChI

1S/C12Br2F8/c13-3-9(19)5(15)1(6(16)10(3)20)2-7(17)11(21)4(14)12(22)8(2)18

InChI key

YXLMNFVUNLCJJY-UHFFFAOYSA-N

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General description

4,4′-Dibromooctafluorobiphenyl undergoes lithiation with n-butyllithium to yield 4,4′-dilithiooctafluorobiphenyl and 4-lithio-4′-bromooctafluorobiphenyl.

Application

4,4′-Dibromooctafluorobiphenyl was used as internal standard to determine brominated flame retardants in sediment samples using on-line combination of pressurised hot water extraction and liquid chromatography-gas chromatography.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN0469
MKCL5785
MKCC8670
MKCC2767
MKBV5206V

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Kati Kuosmanen et al.
Journal of chromatography. A, 943(1), 113-122 (2002-02-01)
Pressurised hot water extraction (PHWE) was coupled on-line with liquid chromatography-gas chromatography (LC-GC) to determine brominated flame retardants in sediment samples. After extraction with pressurised hot water the analytes were adsorbed in a solid-phase trap. The trap was dried with
Yuanyuan Pei et al.
Marine pollution bulletin, 124(2), 1048-1054 (2016-11-09)
The occurrence of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCBs) in urban atmosphere in Guangzhou, China were assessed using homing pigeons as a biomonitor. Contaminant concentrations in lung were significantly higher than those in liver and fat, indicating chemical
Reactions and thermal decomposition of organolithium compounds derived from 4, 4'-dibromooctafluorobiphenyl.
Contigiani RA, et al.
Journal of Organometallic Chemistry, 32(1), 7-15 (1971)
Huizhen Li et al.
Chemosphere, 144, 2427-2435 (2015-11-30)
Commercial mosquito repellents (MRs) are generally applied as mosquito coils, electric vaporizers (liquid and solid) or aerosol spray, with pyrethroids often being the active ingredients. Four types of MRs were applied individually in a 13-m(2) bedroom to study the occurrence
Corie A Fulton et al.
Chemosphere, 222, 489-493 (2019-02-06)
Large-scale honey bee colony loss threatens pollination services throughout the United States. An increase in anthropogenic pressure may influence the exposure of hives to household and agricultural pesticides. The objective of this survey was to provide an assessment of the
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