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459739

Sigma-Aldrich

1-(3-Bromopropyl)-2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane

97%

Synonym(s):

1-(3-Bromopropyl)-2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane

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About This Item

Empirical Formula (Hill Notation):
C9H22BrNSi2
CAS Number:
95091-93-3
Molecular Weight:
280.35
MDL number:
MFCD00274342
UNSPSC Code:
12352100
PubChem Substance ID:
24869593
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.484 (lit.)

bp

80 °C/0.5 mmHg (lit.)

density

1.126 g/mL at 25 °C (lit.)

SMILES string

C[Si]1(C)CC[Si](C)(C)N1CCCBr

InChI

1S/C9H22BrNSi2/c1-12(2)8-9-13(3,4)11(12)7-5-6-10/h5-9H2,1-4H3

InChI key

BKBUBAVZGMRPAK-UHFFFAOYSA-N

Application

1-(3-Bromopropyl)-2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane may be used for the synthesis of PFS-b-PZLys [PFS = Polyferrocenylsilane, PZLys = Poly(epsilon-benzyloxycarbonyl-L-lysine)] block copolymers.

Pictograms

Flame
GHS02

Signal Word

Warning

Hazard Statements

H226

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

95.0 °F - closed cup

Flash Point(C)

35 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Yishan Wang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(28), 8624-8631 (2008-08-01)
A new type of metallopolymer-polypeptide block copolymer poly(ferrocenyldimethylsilane)-b-poly (epsilon-benzyloxycarbonyl-L-lysine) was synthesized by ring-opening polymerization of epsilon-benzyloxycarbonyl-L-lysine N-carboxyanhydride initiated by using a primary amino-terminated poly(ferrocenyldimethylsilane). Studies on the self-organization behavior of this polypeptide block copolymer in both the bulk state and
Synthesis and Characterization of Poly (L-Aspartic Acid)-Based Chimeras using High Vacuum Techniques.
Messman JM, et al.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 47(2), 172-172 (2006)
NANOSTRUCTURES FROM OLIGOPEPTIDE-POLYMER CONJUGATES.
Frauenrath H and Tian L.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 50(2), 533-533 (2009)

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