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Merck
모든 사진(1)

주요 문서

CRM69083

Supelco

Dinoseb

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

동의어(들):

2-sec-Butyl-4,6-dinitrophenol

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About This Item

실험식(Hill 표기법):
C10H12N2O5
CAS Number:
Molecular Weight:
240.21
MDL number:
UNSPSC 코드:
41116107
NACRES:
NA.24

Grade

certified reference material

Quality Level

제품 라인

TraceCERT®

grade

TraceCERT®

유통기한

limited shelf life, expiry date on the label

제조업체/상표

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

형식

neat

저장 온도

2-8°C

SMILES string

CCC(C)c1cc(cc(c1O)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C10H12N2O5/c1-3-6(2)8-4-7(11(14)15)5-9(10(8)13)12(16)17/h4-6,13H,3H2,1-2H3

InChI key

OWZPCEFYPSAJFR-UHFFFAOYSA-N

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일반 설명

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Dinoseb is a selective nitrophenolic herbicide used for protection against postemergence of grass and broad-leaf weeds in vegetables, fruits, nuts, and other field crops such as soybeans. In addition, it also finds its use as an insecticide for grapes, and as a seed drying agent. It acts by uncoupling oxidative phosphorylation in mitochondria and inhibiting ATP synthesis.
Under the Regulation (EC) No 1107/2009 and withdrawing the Council Directives 79/117/EEC and 91/414/EEC, dinoseb is not approved for its use as a plant protection product in the European Union (EU). It was also banned for use as a pesticide in the US in 1986 by the US EPA (Environmental Protection Agency). But a default maximum residue limit (MRL) in the range of 0.02 mg/kg to 0.1 mg/kg is set for the presence of dinoseb (measured as a sum of dinoseb, its salts, dinoseb-acetate, and binapacryl) in products of plant and animal origin.

애플리케이션

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The dinoseb CRM may also be used to:
  • Simultaneously determine dinoseb and pendimethalin in surface water samples using optimized direct injection (DI) and solid phase extraction (SPE) coupled to ultra high-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS)
  • Evaluate anodic voltametric analysis of dinoseb in river water samples using a boron doped diamond electrode following cathode pre-treatment and in the presence of cationic surfactants
  • Extract 15 phenols from refinery wastewater samples by dispersive liquid-liquid microextraction (DLLME) technique and identify them by liquid chromatography-photodiode array detector (LC-PDA)
  • Detect chlorophenoxy acid methyl esters and other chlorinated herbicides in peppermint tea, plum, and orange peel extract soft ionization gas chromatography coupled to quadrupole time-of-flight mass spectrometry (GC-QTOFMS)
  • Analyze 32 pesticide residues of four different chemical classes in tea brew and tea leaves samples by a sample treatment method based on metabolomics and liquid chromatography-mass spectrometry (LC-MS)
  • Determine pendimethalin, dinoseb and sodium 5-nitroguaiacolate in vegetable samples by differential pulse voltammetry (DPV) and chemometrics

추천 제품

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

법적 정보

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1

보충제 위험성

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point (°F)

306.9 °F - closed cup

Flash Point (°C)

152.7 °C - closed cup


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Viorica Lopez-Avila et al.
Analytical chemistry insights, 10, 1-9 (2015-02-24)
Gas chromatography with quadrupole time-of-flight mass spectrometry (GC-QTOFMS) and soft ionization generated by a rare-gas plasma is described here for the determination of various chlorophenoxy acid methyl esters and a few chlorinated herbicides. This plasma-based, wavelength-selectable ionization source, which can
Mark R Viant et al.
Aquatic toxicology (Amsterdam, Netherlands), 77(4), 359-371 (2006-02-21)
Pesticide pulses in the Sacramento River, California, originate from storm-water discharges and non-point source aquatic pollution that can last from a few days to weeks. The Sacramento River and its tributaries have historically supported the majority of California's Chinook salmon

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