CRM16869

Diquat metabolite Monopyridone

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• 동의어(들): 1-Oxo-9,10-dihydro-1H-10a-aza-8a-azoniaphenanthrene chloride, 6,7-Dihydro-9-oxo-9H-dipyrido[1,2-a:2′,1′-c]pyrazin-5-ium chloride
• 실험식(Hill 표기법): C₁₂H₁₁ClN₂O
• Molecular Weight: 234.68
• UNSPSC 코드: 41116107
• NACRES: NA.24

속성

• Grade: certified reference material
• Quality Level: 300
• 제품 라인: TraceCERT^®
• grade: TraceCERT^®
• 유통기한: limited shelf life, expiry date on the label
• 제조업체/상표: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• 형식: neat
• 저장 온도: 2-8°C
• SMILES string: O=C1N2CC[N+]3=CC=CC=C3C2=CC=C1.[Cl-]

설명

일반 설명

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Diquat monopyridone is a common degradation product of Diquat. Diquat is a nonselective, defoliant, preharvest, and desiccant herbicide that belongs to the bipyridinium class. Diquat can rapidly penetrate through the leaf surface but is not taken up by the roots, due to its strong adsorption onto the soil particles. Its activity is based on the liberation of the superoxide anion radical, followed by hydrogen peroxide, causing tissue destruction by oxidative stress. The herbicidal activity of diquat is more pronounced in daylight, aerobic conditions, high humidity, and temperature.

Diquat is not approved for its use in the European Union. The maximum residue limit (MRL) for diquat presence in the crops varies between 0.05 mg/kg in most of the commodities to 10 mg/kg for linseed and barley.

The EU residue definitions are broader, however, the toxicological data is still missing for the diquat metabolites, monopyridone and dipyridone, to compare their toxicity with the parent compound.

애플리케이션

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques. The CRM may also find following uses:

• Detection of two diquat metabolites in urine and serum of poisoned patients after ingestion of combined herbicides, paraquat and diquat
• Analysis of paraquat, diquat, and two diquat metabolites in biological materials by high-performance liquid chromatography coupled with UV and fluorescence detectors

법적 정보

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS06,GHS08,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H301 + H311,H315,H317,H319,H330,H335,H372,H410
• 예방조치 성명서: P273 - P280 - P302 + P352 + P312 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Oral - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 2
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable