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Merck
모든 사진(1)

주요 문서

24308

Supelco

β-DEX 325

L × I.D. 30 m × 0.25 mm, df 0.25 μm

동의어(들):

β-DEX 325, 30M .25MM .25UM

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About This Item

UNSPSC 코드:
41115710
eCl@ss:
32119290

material

fused silica

설명

GC capillary column

파라미터

30-230 °C temperature

베타 값

250

df

0.25 μm

기술

gas chromatography (GC): suitable

길이 × I.D.

30 m × 0.25 mm

기질 활성군

non-bonded; 25% 2,3-di-O-methyl-6-O-TBDMS-β-cyclodextrin in SPB-20 poly(20% phenyl/80% dimethylsiloxane) phase

응용 분야

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

컬럼 유형

capillary chiral

분리 기술

chiral

일반 설명

The chiral stationary phase in β-DEX 325 columns contains 2,3-di-O-methyl-6-0-TBDMS-β-cyclodextrin embedded in an intermediate polarity phase. The Supelco β-DEX 325 is similar in both chemistry and use to the CHIRALDEX B-DM phase, the main difference being the concentration of the dimethyl-derivatized cyclodextrin that is doped into the polysiloxane carrier.

애플리케이션

ß-DEX-325 column was used in gas-liquid chromatography (GLC), for determination of (R)-1-O-acetyl-2-ethyl-1,3-propanediol, formed from 2-Ethyl-1,3-propanediol 1 and its related di-O-acetate, by partial chemoenzymatic acetylation and deacetylation, by Pseudomonas fluorescens lipase. ß -Dex-325 capillary column was also used for resolving 8-acetoxylinalool enantiomers, in an experimental study done in order to study the origin of the enantioselectivity in the biosynthesis of the lilac compounds in Actinidia arguta flowers.

화학적/생리학적 저항성

Temp. Limits:
  • 30 °C to 230 °C

기타 정보

We offer a variety of chromatography accessories including analytical syringes

법적 정보

DEX is a trademark of Sigma-Aldrich Co. LLC

애플리케이션


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문서 라이브러리 방문

A J Matich et al.
Phytochemistry, 68(13), 1746-1751 (2007-05-01)
Biosynthesis of lilac compounds in 'Hortgem Tahi' kiwifruit (Actinidia arguta) flowers was investigated by treating inflorescences with d(5)-linalool. The incorporation of the deuterium label into 8-hydroxylinalool, 8-oxolinalool, the lilac aldehydes, alcohols, and alcohol epoxides was followed by GC-MS and enantioselective
Chiral building-blocks by chemoenzymatic desymmetrization of 2-ethyl-1, 3-propanediol for the preparation of biologically active natural products.
Isidoro I
Tetrahedron Asymmetry, 10 (3), 449-455 (1999)

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