추천 제품
material
fused silica
설명
GC capillary column
파라미터
30-230 °C temperature
베타 값
250
df
0.25 μm
기술
gas chromatography (GC): suitable
길이 × I.D.
30 m × 0.25 mm
기질 활성군
non-bonded; 25% 2,3-di-O-methyl-6-O-TBDMS-β-cyclodextrin in SPB-20 poly(20% phenyl/80% dimethylsiloxane) phase
응용 분야
agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)
컬럼 유형
capillary chiral
분리 기술
chiral
일반 설명
The chiral stationary phase in β-DEX 325 columns contains 2,3-di-O-methyl-6-0-TBDMS-β-cyclodextrin embedded in an intermediate polarity phase. The Supelco β-DEX 325 is similar in both chemistry and use to the CHIRALDEX B-DM phase, the main difference being the concentration of the dimethyl-derivatized cyclodextrin that is doped into the polysiloxane carrier.
애플리케이션
ß-DEX™-325 column was used in gas-liquid chromatography (GLC), for determination of (R)-1-O-acetyl-2-ethyl-1,3-propanediol, formed from 2-Ethyl-1,3-propanediol 1 and its related di-O-acetate, by partial chemoenzymatic acetylation and deacetylation, by Pseudomonas fluorescens lipase. ß -Dex™-325 capillary column was also used for resolving 8-acetoxylinalool enantiomers, in an experimental study done in order to study the origin of the enantioselectivity in the biosynthesis of the lilac compounds in Actinidia arguta flowers.
화학적/생리학적 저항성
Temp. Limits:
- 30 °C to 230 °C
기타 정보
We offer a variety of chromatography accessories including analytical syringes
법적 정보
DEX is a trademark of Sigma-Aldrich Co. LLC
이미 열람한 고객
A J Matich et al.
Phytochemistry, 68(13), 1746-1751 (2007-05-01)
Biosynthesis of lilac compounds in 'Hortgem Tahi' kiwifruit (Actinidia arguta) flowers was investigated by treating inflorescences with d(5)-linalool. The incorporation of the deuterium label into 8-hydroxylinalool, 8-oxolinalool, the lilac aldehydes, alcohols, and alcohol epoxides was followed by GC-MS and enantioselective
Chiral building-blocks by chemoenzymatic desymmetrization of 2-ethyl-1, 3-propanediol for the preparation of biologically active natural products.
Isidoro I
Tetrahedron Asymmetry, 10 (3), 449-455 (1999)
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