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일반 설명
Sodium persulfate, also known as Sodium peroxodisulfate is an inorganic compound and is a water-soluble strong oxidizing agent, that is stable and easy to handle. It is commonly used as an oxidant in organic synthesis reactions such as transition-metal-catalyzed or metal-free reactions. Additionally, it is used as a polymerization initiator and in the synthesis of sulfate radical anions through heat-activated decomposition.
애플리케이션
Sodium persulfate can be used as an oxidant:
- For the radical cyclization cascade reaction of 2-alkynylbenzonitriles and sodium arylsulfinates to synthesize sulfonated indenones.
- In the silica-supported aluminum chloride-catalyzed Baeyer-Villiger oxidation of cyclic and acyclic ketones to lactones or esters.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
이미 열람한 고객
Esther Eljarrat-Binstock et al.
Investigative ophthalmology & visual science, 45(8), 2543-2548 (2004-07-28)
To assess the corneal iontophoretic delivery of gentamicin by drug-loaded hydrogel probe, and to determine the resultant ocular disposition and elimination of the drug from the cornea and anterior chamber. Corneal iontophoresis of gentamicin sulfate was studied in healthy white
N Sabri et al.
The Science of the total environment, 427-428, 382-389 (2012-05-15)
The objective of this work was to evaluate the removal of ibuprofen (IBP) using the oxidants hydrogen peroxide (H(2)O(2)) and sodium persulfate (Na(2)S(2)O(8)). The ability of magnetite (Fe(3)O(4)) to activate persulfate (PS) and H(2)O(2) for the oxidation of IBP at
Mushtaque Ahmad et al.
Journal of contaminant hydrology, 115(1-4), 34-45 (2010-05-05)
Persulfate dynamics in the presence of subsurface minerals was investigated as a basis for understanding persulfate activation for in situ chemical oxidation (ISCO). The mineral-mediated decomposition of persulfate and generation of oxidants and reductants was investigated with four iron and
Aikaterini Tsitonaki et al.
Water research, 42(4-5), 1013-1022 (2007-10-19)
The effects of heat-activated persulfate on indigenous microorganisms and microcosms augmented with Pseudomonas putida KT2440 were studied in laboratory batch reactors with aquifer material. Microscopic enumeration was used to measure the changes in cell density, and acetate consumption was used
Richard L Johnson et al.
Environmental science & technology, 42(24), 9350-9356 (2009-01-30)
Contaminant destruction with in situ chemical oxidation (ISCO) using persulfate (peroxydisulfate, S2O8(2-)) can be enhanced by activation, which increases the rate of persulfate decomposition to sulfate radicals (SO4*-). This step initiates a chain of radical reactions involving species (including SO4*-
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