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Merck
모든 사진(3)

주요 문서

208396

Sigma-Aldrich

Cobalt(II) acetate tetrahydrate

reagent grade

동의어(들):

Cobaltous acetate tetrahydrate

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About This Item

Linear Formula:
(CH3COO)2Co · 4H2O
CAS Number:
Molecular Weight:
249.08
Beilstein:
3731397
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.55
Grade:
reagent grade
양식:
powder or crystals

Grade

reagent grade

Quality Level

양식

powder or crystals

농도

23.0-25.0% Co (EDTA titration)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Co]OC(C)=O

InChI

1S/2C2H4O2.Co.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2

InChI key

ZBYYWKJVSFHYJL-UHFFFAOYSA-L

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일반 설명

Cobalt(II) acetate tetrahydrate, commonly used as bleach and drying agent, can be produced by reacting cobalt (II) carbonate and acetic acid. It undergoes decomposition on heating up to 500°C under non-isothermal conditions. Its crystals exhibit monoclinic crystal system having space group P21/c. Cobalt(II) acetate tetrahydrate undergoes hydrothermal reaction with 1,3,5-benzenetricarboxylic acid (BTCH3) to afford Co3(BTC)2.12H2O.

애플리케이션

Cobalt(II) acetate tetrahydrate may be used as a cobalt source in the synthesis of cobalt nanoparticles and cobalt oxide thin films. It may also be used to prepare cobalt(II)-aminophenyltetrazolate coordination polymer and tricobalt complexes with mixed μ-acetato and μ-pyrazolato ligands. Cobalt(II) acetate tetrahydrate enhances the reaction rate of oxidation of 1,4-dihydropyridines using hydrogen peroxide to the corresponding pyridine derivatives.
Cobalt(II) acetate tetrahydrate may be used in the preparation of [Co3(OH)2(H2O)2(aptet)4] (aptet = 4-aminophenyltetrazolate) and new tetradentate cobalt(II)-Schiff base complex.

픽토그램

Health hazardExclamation markEnvironment

신호어

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Irrit. 2 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3


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문서 라이브러리 방문

Synthesis, characterization, and electrochemical behavior of a cobalt (II) salen-like complex.
Ourari A, et al.
Polyhedron, 97, 197-201 (2015)
Aromatization of Hantzsch 1, 4-dihydropyridines by hydrogen peroxide in the presence of cobalt (II) acetate.
Hashemi MM, et al.
Monatshefte fur Chemie / Chemical Monthly, 134(1), 107-110 (2003)
Cobalt nanoparticles synthesis from Co(CH3COO)2 by thermal decomposition.
Shao H, et al.
Journal of magnetism and magnetic materials, 304(1), e28-e30 (2006)
The non-isothermal decomposition of cobalt acetate tetrahydrate: a kinetic and thermodynamic study.
Mohamed M, et al.
Journal of Thermal Analysis and Calorimetry, 1(2-3), 387-404 (1994)
Chemical accuracy and precision in Rietveld analysis: The crystal structure of cobalt (II) acetate tetrahydrate.
Kaduk JA and Walt Partenheimer.
Powder Diffraction, 12(01), 27-39 (1997)

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