L3900

2,6-Lutidine

ReagentPlus^®, 98%

• 동의어(들): 2,6-Dimethylpyridine
• 실험식(Hill 표기법): C₇H₉N
• CAS Number: 108-48-5
• Molecular Weight: 107.15
• Beilstein: 105690
• EC Number: 203-587-3
• MDL number: MFCD00006345
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24896359
• NACRES: NA.22

속성

• Quality Level: 200
• 제품 라인: ReagentPlus^®
• 분석: 98%
• refractive index: n20/D 1.497 (lit.)
• bp: 143-145 °C (lit.)
• mp: −6 °C (lit.)
• density: 0.92 g/mL at 25 °C (lit.)
• SMILES string: Cc1cccc(C)n1
• InChI: 1S/C7H9N/c1-6-4-3-5-7(2)8-6/h3-5H,1-2H3
• InChI key: OISVCGZHLKNMSJ-UHFFFAOYSA-N

설명

애플리케이션

2,6-Lutidine can be used as a base for the oxidation of α-CF₃ alcohols to the corresponding carbonyl compounds in the presence of 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (Bobbitt′s salt) as oxidation reagent.
It can be used:

• As a promoter for catalytic asymmetric fluorination of α-cyanophosphonates in the presence of chiral Pd(II)-bisphosphine complexes.
• In combination with tert-butyldimethylsilyl triflate for the protection of tertiary alcohols and unreactive secondary alcohols.
• In combination with triethylsilyl trifluoromethanesulfonate for the conversion of acetals to the corresponding aldehydes in dichloromethane followed by workup in water.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H302,H315,H319
• 예방조치 성명서: P210 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 91.4 °F
• Flash Point (°C): 33 °C
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter