33233

Hexamethylenetetramine

puriss. p.a., reag. Ph. Eur., ≥99.5% (calc. to the dried substance)

• 동의어(들): 1,3,5,7-Tetraazatricyclo[3.3.1.1^3,7]decane, Hexamine, Methenamine, Urotropine
• 실험식(Hill 표기법): C₆H₁₂N₄
• CAS Number: 100-97-0
• Molecular Weight: 140.19
• Beilstein: 2018
• EC Number: 202-905-8
• MDL number: MFCD00006895
• UNSPSC 코드: 12352100
• PubChem Substance ID: 57648782
• NACRES: NA.21

속성

• Agency: USP/NF; reag. Ph. Eur.
• Quality Level: 100
• vapor pressure: <0.01 mmHg ( 20 °C)
• grade: puriss. p.a.
• 분석: ≥99.5% (calc. to the dried substance)
• 형태: solid
• autoignition temp.: 770 °F
• 불순물: ≤0.001% heavy metals (as Pb); ≤0.01% ammonium (NH₄)
• 무기 잔류물: ≤0.01% (as SO₄)
• pH: 8.5-9.5 (20 °C, 10%)
• mp: 280 °C (subl.) (lit.)
• solubility: H₂O: soluble
• 음이온 미량물: chloride (Cl^-): ≤20 mg/kg; sulfate (SO₄^2-): ≤50 mg/kg
• SMILES string: C1N2CN3CN1CN(C2)C3
• InChI: 1S/C6H12N4/c1-7-2-9-4-8(1)5-10(3-7)6-9/h1-6H2
• InChI key: VKYKSIONXSXAKP-UHFFFAOYSA-N

설명

일반 설명

Hexamethylenetetramine is a hexamine. It participates in Duff reaction for the synthesis of o-hydroxybenzaldehyde derivatives.

애플리케이션

Hexamethylenetetramine may be used as reagent in the synthesis of 3 and 5-aldehydo salicylic acid, and 2-hydroxy naphthaldehyde, via reaction with salicylic acid and β-naphthol respectively, followed by the treatment with HCl (hydrolysis). It may be used for the synthesis of phenolic aldehydes. It may be used as formylating reagent for the synthesis of various aldehydes.
It has been used for the preparation of ceria nanoparticles, via precipitation method.

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H228,H317
• 예방조치 성명서: P210 - P240 - P241 - P261 - P280 - P302 + P352
• Hazard Classifications: Flam. Sol. 2 - Skin Sens. 1B
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 1
• Flash Point (°F): 482.0 °F - closed cup
• Flash Point (°C): 250 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges