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일반 설명
Bis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.
애플리케이션
Bis(trifluoromethane)sulfonamide may be used in the following studies:
- As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
- As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
- Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
- As a component of solid polymer electrolytes.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1
Storage Class Code
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
Self-assembly of cationic rod-like poly (2, 5-pyridine) by acidic bis (trifluoromethane) sulfonimide in the hydrated state: A highly-ordered self-assembled protonic conductor.
Polymer, 51(18), 4095-4102 (2010)
Comparative Electrochemical Study of New Poly(oxyethylene)-Li Salt Complexes.
J. Chem. Soc., Faraday, 89, 355-359 (1993)
Synthesis of trehalose mimics by bismuth (III) triflate or bis (trifluoromethane) sulfonimide-catalyzed 1-C-methyl-D-hexopyranosylation.
Tetrahedron Asymmetry, 17(20), 2914-2918 (2006)
Bis (trifluoromethane) sulfonimide initiated ring-opening polymerization of octamethylcyclotetrasiloxane.
Journal of Organometallic Chemistry, 646(1), 171-178 (2002)
Gas transport properties of Pebax?/room temperature ionic liquid gel membranes.
Separation and Purification Technology, 97, 73-82 (2012)
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