8.22287

Hydrogen peroxide solution

30%, (stabilized) for synthesis

• 동의어(들): Hydrogen peroxide solution, Perhydrol
• 실험식(Hill 표기법): H₂O₂
• CAS Number: 7722-84-1
• Molecular Weight: 34.01
• Beilstein: 3587191
• MDL number: MFCD00011333
• UNSPSC 코드: 12352304
• NACRES: NA.22

속성

• product name: Hydrogen peroxide 30%, (stabilized) for synthesis
• vapor pressure: 18 hPa ( 20 °C); 23.3 mmHg ( 30 °C)
• Quality Level: 200
• 형태: liquid
• 반응 적합성: reagent type: oxidant
• pH: 2-4 (20 °C in H₂O)
• bp: 107 °C/1013 hPa
• mp: -26 °C
• density: 1.11 g/cm³ at 20 °C
• 저장 온도: 2-25°C
• SMILES string: OO
• InChI: 1S/H2O2/c1-2/h1-2H
• InChI key: MHAJPDPJQMAIIY-UHFFFAOYSA-N

설명

애플리케이션

Hydrogen peroxide 30% can be used as an oxidizing agent:

• To synthesize 5-bromo-2-nitropyridine from 5-bromo-2-aminopyridine in the presence of H₂SO₄.
• For the oxidation of aromatic and aliphatic sulfides to sulfoxides or sulfones.
• For the epoxidation of terminal olefins using a mixture of Na₂WO₄ dihydrate, (aminomethyl)phosphonic acid, and methyltrin-octylammonium hydrogensulfate.
• To prepare adipic acid via oxidation of cyclohexanone and cyclohexanol in the presence of H₂WO₄ as a catalyst.
• To convert cyclopentanone to δ-valerolactone via Baeyer−Villiger-oxidation in the presence of a solid acid catalyst.

분석 메모

Assay (manganometric): 29.0 - 31.0 %
Density (d 20/4): 1.11 - 1.12 g/cm³

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H318
• 예방조치 성명서: P280 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 1
• Flash Point (°F): not combustible
• Flash Point (°C): not combustible