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Merck
모든 사진(1)

주요 문서

T58009

Sigma-Aldrich

Tridecylamine

98%

동의어(들):

1-Aminotridecane

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About This Item

Linear Formula:
CH3(CH2)12NH2
CAS Number:
Molecular Weight:
199.38
Beilstein:
1739990
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

98%

bp

265 °C (lit.)

mp

30-32 °C (lit.)

SMILES string

CCCCCCCCCCCCCN

InChI

1S/C13H29N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14/h2-14H2,1H3

InChI key

ABVVEAHYODGCLZ-UHFFFAOYSA-N

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애플리케이션

Tridecylamine can undergo:
  • Dehydrogenation to nitriles catalyzed by ruthenium complex.
  • Aerobic oxidation to carbonyl compounds catalyzed by vitamin C and Cu complex.

Tridecylamine is generally used in introducing C13 chain to the substrate. Some of the application are:
  • Synthesis of alkylated 1,2,4-triazoles as bridging ligand in the preparation of polymeric 1-dimensional chains of iron(II) species.
  • Synthesis of amphiphiles such as N-tridecyl-β-hydroxypropionic acid amide (THPA) and N-(β-hydroxyethyl)tridecanoic acid amide (HETA).
  • As a ligand in the preparation of palladium-based catalyst, [PdCl2(TDA)2].

픽토그램

CorrosionExclamation markEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

230.0 °F - closed cup

Flash Point (°C)

110 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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시험 성적서(COA)

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문서 라이브러리 방문

Copper/ascorbic acid dyad as a catalytic system for selective aerobic oxidation of amines
Srogl J and Voltrova S
Organic Letters, 11(4), 843-845 (2009)
Double Dehydrogenation of Primary Amines to Nitriles by a Ruthenium Complex Featuring Pyrazole Functionality
Dutta I, et al.
Journal of the American Chemical Society, 140(28), 8662-8666 (2018)
Spin-transition behaviour in chains of Fe II bridged by 4-substituted 1, 2, 4-triazoles carrying alkyl tails,.
Roubeau O, et al.
New. J. Chem., 25(1), 144-150 (2001)
Catalytic investigation of PdCl2 (TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction.
Mastalir A, et al.
Reaction Kinetics, Mechanisms and Catalysis, 113(1), 61-68 (2014)
1-Heptyne semihydrogenation catalized by palladium or rhodium complexes: Influence of: metal atom, ligands and the homo/heterogeneous condition.
Quiroga M E, et al.
Applied Catalysis A: General, 326(2), 121-129 (2007)

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