추천 제품
분석
97%
형태
liquid
refractive index
n20/D 1.419 (lit.)
bp
112-113 °C (lit.)
density
1.187 g/mL at 25 °C (lit.)
저장 온도
2-8°C
SMILES string
COCC(Cl)=O
InChI
1S/C3H5ClO2/c1-6-2-3(4)5/h2H2,1H3
InChI key
JJKWHOSQTYYFAE-UHFFFAOYSA-N
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애플리케이션
Methoxyacetyl chloride can be used for methoxyacetylation of:
It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO2 with propylene oxide.
- Bilocularin A to synthesize 8-Methoxyacetoxybilocularin A.
- Substituted and unsubstituted benzamides to synthesize N-(2-methoxyacetyl)-benzamides.
It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO2 with propylene oxide.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
82.4 °F
Flash Point (°C)
28 °C
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
A telescopic one-pot synthesis of ?-lactam rings using amines as a convenient source of imines.
Rajamaki SHM, et al.
Royal Society of Chemistry Advances, 6(45), 38553-38557 (2016)
Bioactive dihydro-?-agarofuran sesquiterpenoids from the Australian rainforest plant Maytenus bilocularis.
Wibowo M, et al.
Journal of Natural Products, 79(5), 1445-1453 (2016)
Functionalized MIL-101 with imidazolium-based ionic liquids for the cycloaddition of CO2 and epoxides under mild condition.
Liu D, et al.
Applied Surface Science, 428(45), 218-225 (2018)
Radu A Gropeanu et al.
PloS one, 7(9), e43657-e43657 (2012-09-13)
Three different variants of photoactivatable caged paclitaxel (PTX) have been synthesized and their bioactivity was characterized in in vitro assays and in living cells. The caged PTXs contain the photoremovable chromophore 4,5-dimethoxy-2-nitrobenzyloxycarbonyl (Nvoc) attached to position C7, C2' and to
Synthesis of Quinolinone Alkaloids via Aryne Insertions into Unsymmetric Imides in Flow.
Schwan J, et al.
Organic Letters, 20(23), 7661?7664-7661?7664 (2018)
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