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Merck
모든 사진(1)

주요 문서

D145750

Sigma-Aldrich

N,N-Dimethylaniline

99%

동의어(들):

N,N-Dimethylphenylamine, DMA, Dimethylaniline, Dimethylphenylamine

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About This Item

Linear Formula:
C6H5N(CH3)2
CAS Number:
Molecular Weight:
121.18
Beilstein:
507140
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:

Quality Level

분석

99%

형태

liquid

refractive index

n20/D 1.557 (lit.)

bp

193-194 °C (lit.)

mp

1.5-2.5 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

작용기

amine

SMILES string

CN(C)c1ccccc1

InChI

1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

JLTDJTHDQAWBAV-UHFFFAOYSA-N

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일반 설명

N,N-dimethylaniline (DMA) is N,N-disubstituted aniline. The thermo-physical and thermodynamic properties of the binary mixtures of DMA with anisole (ANS) and tert-butyl methyl ether (MTBE) have been reported. In acidic buffers it forms N,N,N′,N′-tetramethylbenzidine at a platinum electrode due anodic oxidation. DMA combines with diazonium salts to form methyl orange under alkaline condition. It forms ortho- and para-nitro derivatives via nitration reaction using N-bromosuccinimide/silver(I) nitrate reagent system in acetonitrile.

애플리케이션

N,N-dimethylaniline (DMA) may be used as a catalyst for reductive lithiation.
Reagent in new methodology for symmetrical and unsymmetrical photoconductor squaranes.

법적 정보

DuPont product

교체됨

제품 번호
설명
가격

픽토그램

Skull and crossbonesHealth hazardEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point (°F)

167.0 °F - closed cup

Flash Point (°C)

75 °C - closed cup


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문서 라이브러리 방문

Canadian Journal of Chemistry, 71, 494-494 (1993)
Spectrophotometric determination of chromium by using sulphanilic acid and N, N-dimethylaniline.
Chandrashekhara KG, et al.
Indian Journal of Chemical Technology, 22(1-2), 78-81 (2015)
Molecular interaction study through experimental and theoretical volumetric, acoustic and refractive properties of binary liquid mixtures at several temperatures 1. N,N-dimethylaniline with aryl, and alkyl ethers.
Master ZR and Malek NI.
Journal of Molecular Liquids, 196, 120-134 (2014)
Fundamental Difference in Reductive Lithiations with Preformed Radical Anions versus Catalytic Aromatic Electron-Transfer Agents: N,N-Dimethylaniline as an Advantageous Catalyst.
Kennedy N, et al.
Angewandte Chemie (International Edition in English), 128(1), 391-394 (2016)
Aromatic nitration under neutral conditions using N-bromosuccinimide/silver (I) nitrate.
Nowrouzi N, et al.
Tetrahedron Letters, 53(36), 4841-4842 (2012)

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