923508

(iPrMPhos)PdCl₂

1:1 complex with CH₂Cl₂, ≥95%

• 동의어(들): 1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride
• 실험식(Hill 표기법): C₃₆H₅₂Cl₂FeP₂Pd
• Molecular Weight: 779.92

속성

• Quality Level: 100
• 분석: ≥95%
• 형태: powder
• 반응 적합성: reagent type: catalyst; reaction type: Cross Couplings
• mp: >300 °C
• SMILES string: Cl[Pd](Cl)([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)[P](c8cccc8)(C(C)C)C(C)C.[Fe]

설명

애플리케이션

(iPrMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

기타 정보

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable