추천 제품
설명
Fp: 175°F
Quality Level
분석
95% (GC)
형태
liquid
반응 적합성
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation
refractive index
n/D 1.516
density
0.9800 g/mL at 25 °C
작용기
amine
SMILES string
NC(C)(C)C1=CC=CC=N1
InChI
1S/C8H12N2/c1-8(2,9)7-5-3-4-6-10-7/h3-6H,9H2,1-2H3
InChI key
DQSQBZXDMHDHEO-UHFFFAOYSA-N
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일반 설명
2-(Pyridin-2-yl)isopropyl amine (PIP-amine) is a tertiary amine. A bidentate directing group, useful for the functionalization of C-H bond, has been developed from PIP-amine.
애플리케이션
The Shi Auxiliary is a powerful directing group for the hydroxylation of arenes through copper-mediated C-H activation. This useful auxiliary can be removed through acid-mediated hydrolysis and has shown to be done on gram-scale.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
175.0 °F
Flash Point (°C)
79.44 °C
가장 최신 버전 중 하나를 선택하세요:
Organic letters, 16(15), 3904-3907 (2014-07-17)
A copper-mediated C-H hydroxylation of arenes and heteroarenes using our newly developed PIP directing group has been developed. This procedure is scalable and compatible with a wide range of functional groups and heteroarenes, providing an operationally simple protocol for the
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