추천 제품
분석
95%
형태
liquid
refractive index
n20/D 1.374
density
0.666 g/mL at 25 °C (lit.)
저장 온도
2-8°C
SMILES string
C#CC(C)C
InChI
1S/C5H8/c1-4-5(2)3/h1,5H,2-3H3
InChI key
USCSRAJGJYMJFZ-UHFFFAOYSA-N
관련 카테고리
애플리케이션
3-Methyl-1-butyne can be used as a reactant in the ruthenium-catalyzed synthesis of functionalized cycloheptadienes and titanium-catalyzed [2+2+1] multicomponent pyrrole synthesis. It is also used as a precursor in the total syntheses of (+)-frondosin A, (−)-citrinadin A, (+)-citrinadin B and coraxeniolide A.
3-Methyl-1-butyne is a terminal alkyne that can be used to prepare:
- Maleimide-fused cyclopentenones by reacting with N-substituted maleimides via Co2(CO)8-mediated Pauson−Khand reaction.
- An alkyne carboxylic acid (Alkyne Segment C) intermediate, which is used in the total synthesis of oscillatoxin D and its analogs.
이미 열람한 고객
Enantioselective total synthesis of (-)-citrinadin A and revision of its stereochemical structure.
Journal of the American Chemical Society, 135(30), 10886-10889 (2013)
Synthetic Route to Oscillatoxin D and Its Analogues
Organic Letters, 19(21), 5992-5995 (2017)
Total synthesis of (+)-frondosin A. Application of the Ru-catalyzed [5+ 2] cycloaddition.
Journal of the American Chemical Society, 129(38), 11781-11790 (2007)
Metal carbene-promoted sequential transformations for the enantioselective synthesis of highly functionalized cycloheptadienes.
Journal of the American Chemical Society, 127(5), 1342-1343 (2005)
An unconventional approach to the enantioselective synthesis of caryophylloids.
Journal of the American Chemical Society, 130(10), 2954-2955 (2008)
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