추천 제품
Quality Level
분석
97%
형태
solid
반응 적합성
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
218-220 °C
저장 온도
2-8°C
SMILES string
Cl[Pd].Cl[Pd].[CH2][CH][CH]c1ccccc1.[CH2][CH][CH]c2ccccc2
InChI
1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q;;;;2*+1/p-2
InChI key
SHWAPUDBEQXXLQ-UHFFFAOYSA-L
애플리케이션
Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
It can also be used as a source of palladium in the asymmetric α-arylation of amides.
- Ammonia cross-coupling reactions to synthesize arylamines.
- Conversion of aryl triflates to fluorides.
It can also be used as a source of palladium in the asymmetric α-arylation of amides.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
이미 열람한 고객
Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.
Journal of the American Chemical Society, 133(45), 18106-18109 (2011)
Matching the chirality of monodentate N-heterocyclic carbene ligands: a case study on well-defined palladium complexes for the asymmetric ?-arylation of amides.
Organic Letters, 10(24), 5569-5572 (2008)
AP, N?Ligand for Palladium?Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Arylations, and Room Temperature Reactions
Angewandte Chemie (International Edition in English), 122(24), 4165-4168 (2010)
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