704059
2,6-Bis((S)-4,5-dihydro-4-phenethyloxazol-2-yl)pyridine
97%
동의어(들):
(S)-BnCH2-PyBox, (S,S)-2,6-Bis(4-benzylmethyl-2-oxazolin-2-yl)pyridine
로그인조직 및 계약 가격 보기
모든 사진(2)
About This Item
실험식(Hill 표기법):
C27H27N3O2
CAS Number:
Molecular Weight:
425.52
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22
추천 제품
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![2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine 98%](/deepweb/assets/sigmaaldrich/product/structures/372/262/fb5c79fe-8277-48b0-a73e-4124c7c2c41c/640/fb5c79fe-8277-48b0-a73e-4124c7c2c41c.png)
![2,6-Bis[(4S,5S)-4-methyl-5-phenyl-2-oxazolinyl]pyridine 98%](/deepweb/assets/sigmaaldrich/product/structures/677/633/5f588f23-ca3b-4529-b05e-16510ee03731/640/5f588f23-ca3b-4529-b05e-16510ee03731.png)
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Quality Level
분석
97%
형태
powder
광학 활성
[α]22/D −75, c = 1 in chloroform
mp
154-158 °C
SMILES string
C(Cc1ccccc1)[C@H]2COC(=N2)c3cccc(n3)C4=N[C@@H](CCc5ccccc5)CO4
InChI
1S/C27H27N3O2/c1-3-8-20(9-4-1)14-16-22-18-31-26(28-22)24-12-7-13-25(30-24)27-29-23(19-32-27)17-15-21-10-5-2-6-11-21/h1-13,22-23H,14-19H2/t22-,23-/m0/s1
InChI key
IYRZZMJRGHERQU-GOTSBHOMSA-N
애플리케이션
Ligand for asymmetric Negishi cross-coupling of secondary allylic chlorides
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
가장 최신 버전 중 하나를 선택하세요:
이미 열람한 고객
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Sunghee Son et al.
Journal of the American Chemical Society, 130(9), 2756-2757 (2008-02-09)
Complementing previous advances in allylation chemistry, an effective nickel/Pybox catalyst for regioselective asymmetric Negishi cross-couplings of racemic secondary allylic chlorides with readily available organozinc halides has been developed. The method has been applied in two key steps of a formal
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