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Merck
모든 사진(3)

주요 문서

683183

Sigma-Aldrich

CARAC

Umicore, 98%

동의어(들):

Dicarbonyl-acetylacetonato-rhodium(I), (Acetylacetonato)dicarbonylrhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rh(CO)2acac, Rhodium(I) dicarbonyl acetylacetonate

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About This Item

Linear Formula:
Rh(CO)2(C5H7O2)
CAS Number:
Molecular Weight:
258.03
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

98%

형태

solid

반응 적합성

core: rhodium
reagent type: catalyst

mp

154-156 °C (lit.)

SMILES string

[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]

InChI

1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;

InChI key

BZCAWKOPWNIDOC-FGSKAQBVSA-M

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds

법적 정보

Product of Umicore

Additional information available at www.pmc.umicore.com

픽토그램

FlameSkull and crossbonesEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Sens. 1

보충제 위험성

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Breit, B.; Seiche, W.,
Synthesis, 1-1 (2001)
Ojima, I.; Lee, S.-Y.
Journal of the American Chemical Society, 122, 2385-2385 (2000)
D Bonafoux et al.
Organic letters, 3(9), 1303-1305 (2001-05-12)
[reaction in text] Desymmetrization of dimethylsilyloxyalkadiynes (1) by Rh-catalyzed intramolecular silylformylation affords 5-exo-(formylmethylene)oxasilacyclopentanes 2 in high yields. Novel sequential double silylformylation of 1a also provides desymmetrization, giving 3-(3-silyl-2-formylprop-2-enyl)-5-exo-(formylmethylene)oxasilacyclopentanes 4 in excellent yields. Reduction of 2a and 4 with NaBH(4) gives
K A Merchant et al.
Physical review letters, 86(17), 3899-3902 (2001-05-01)
2D spectrally resolved ultrafast (<200 fs) IR vibrational echo experiments were performed on Rh(CO)(2)acac [(acetylacetonato)dicarbonylrhodium (I)]. The 2D spectra display features that reflect the 0-1 and 1-2 transitions and the combination band transition of the symmetric (S) and antisymmetric (A)
Andrei V Pakoulev et al.
The journal of physical chemistry. A, 112(28), 6320-6329 (2008-06-25)
Triply vibrationally enhanced four-wave mixing spectroscopy is employed to observe vibrational coherence transfer between the asymmetric and symmetric CO-stretching modes of rhodium(I) dicarbonyl acetylacetonate (RDC). Coherence transfer is a nonradiative transition of a coherent superposition of quantum states to a

문서

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions. 20 different precatalyst complexes are available, providing access to hundred different catalytic reactions.

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