추천 제품
Quality Level
분석
97%
refractive index
n20/D 1.341 (lit.)
n/D (lit.)
density
1.283 g/mL at 25 °C (lit.)
작용기
ester
fluoro
ketone
SMILES string
CCOC(=O)C(=O)C(F)(F)F
InChI
1S/C5H5F3O3/c1-2-11-4(10)3(9)5(6,7)8/h2H2,1H3
InChI key
KJHQVUNUOIEYSV-UHFFFAOYSA-N
일반 설명
Ethyl 3,3,3-trifluoropyruvate is a trifluoromethylated compound. Enantioselective Friedel–Crafts alkylation of simple phenols and indoles with ethyl 3,3,3-trifluoropyruvate under different reaction conditions have been reported.
애플리케이션
Ethyl 3,3,3-trifluoropyruvate may be used in the preparation of N-heteroaryl(trifluoromethyl)hydroxyalkanoic acid esters.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
87.8 °F - closed cup
Flash Point (°C)
31 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves
Synthesis of N-Heteroaryl (trifluoromethyl) hydroxyalkanoic Acid Esters by Highly Efficient Solid Acid-Catalyzed Hydroxyalkylation of Indoles and Pyrroles with Activated Trifluoromethyl Ketones.
Advanced Synthesis & Catalysis, 347(14), 1797-1803 (2005)
Organocatalytic enantioselective Friedel?Crafts alkylation of simple phenols with trifluoropyruvate.
Tetrahedron Letters, 49(9), 1476-1479 (2008)
Novel Enantiocomplementary C2-Symmetric Chiral Bis (imidazoline) Ligands: Highly Enantioselective Friedel?Crafts Alkylation of Indoles with Ethyl 3, 3, 3-Trifluoropyruvate.
Advanced Synthesis & Catalysis, 350(10), 1443-1448 (2008)
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