469785
Benzyl glycidyl ether
99%
동의어(들):
(Benzyloxymethyl)oxirane, (±)-O-Benzylglycidol, 1-(Benzyloxy)-2,3-epoxypropane, 2-[(Phenylmethoxy)methyl]oxirane, 2-[[(Benzyloxy)methyl]oxy]oxirane, 3-(Benzyloxy)-1,2-epoxypropane, Glycidyl benzyl ether, [(Phenylmethoxy)methyl]oxirane
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모든 사진(1)
About This Item
추천 제품
Quality Level
분석
99%
refractive index
n20/D 1.5170 (lit.)
bp
70-73 °C/11 mmHg (lit.)
density
1.077 g/mL at 25 °C (lit.)
작용기
ether
phenyl
저장 온도
2-8°C
SMILES string
C(OCc1ccccc1)C2CO2
InChI
1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2
InChI key
QNYBOILAKBSWFG-UHFFFAOYSA-N
일반 설명
Benzyl glycidyl ether is a glycidyl derivative. Rac-/(R)-benzyl glycidyl ether participates in the synthesis of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s. Biocatalytic resolution of racemic benzyl glycidyl ether by Talaromyces flavus has been described. Resolution of benzyl glycidyl ether to (S)-benzyl glycidyl ether with 30% ee and (R)-3-benzyloxypropane-1,2-diol with 40% ee by whole Bacillus alcalophilus cells has been reported. It reacts with K-, K+(15-crown-5)2 to afford potassium glycidoxide and bibenzyl.
신호어
Warning
유해 및 위험 성명서
예방조치 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
235.4 °F - closed cup
Flash Point (°C)
113 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
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Journal of the American Chemical Society, 135(18), 6806-6809 (2013-04-25)
The synthesis and characterization of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s are reported. The poly(benzyl 1,2-glycerol carbonate)s were obtained via the ring-opening copolymerization of rac-/(R)-benzyl glycidyl ether with CO2 using [SalcyCo(III)X] complexes with high carbonate linkage selectivity and polymer/cyclic
Selective cleavage of the linear ether bond in benzyl glycidyl ether and triphenylmethyl glycidyl ether by potassium alkalide as two-electron-transfer reagent.
Journal of Organometallic Chemistry, 660(1), 6-13 (2002)
Biotechnology letters, 34(8), 1499-1503 (2012-04-25)
Talaromyces flavus containing a constitutive epoxide hydrolase (EH) resolved racemic benzyl glycidyl ether and nine derivatives into their (R)-enantiomers. After optimization of the fermentation conditions, the specific EH activity and biomass concentration were improved from 13.5 U/g DCW and 14.8
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