446955

Allyltrimethoxysilane

95%

• 동의어(들): Trimethoxy-2-propen-1-ylsilane, trimethoxy-2-propenylsilane
• Linear Formula: H₂C=CHCH₂Si(OCH₃)₃
• CAS Number: 2551-83-9
• Molecular Weight: 162.26
• Beilstein: 2350745
• EC Number: 219-855-8
• MDL number: MFCD00053865
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24868309
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 95%
• 양식: liquid
• refractive index: n20/D 1.405 (lit.)
• bp: 146-148 °C (lit.)
• density: 0.963 g/mL at 25 °C (lit.)
• SMILES string: CO[Si](CC=C)(OC)OC
• InChI: 1S/C6H14O3Si/c1-5-6-10(7-2,8-3)9-4/h5H,1,6H2,2-4H3
• InChI key: LFRDHGNFBLIJIY-UHFFFAOYSA-N

설명

애플리케이션

Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H315,H319,H335
• 예방조치 성명서: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 114.8 °F - closed cup
• Flash Point (°C): 46 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter