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Merck
모든 사진(4)

문서

383317

Sigma-Aldrich

Zinc acetate

99.99% trace metals basis

동의어(들):

Zn(OAc)2

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About This Item

Linear Formula:
(CH3CO2)2Zn
CAS Number:
Molecular Weight:
183.48
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

99.99% trace metals basis

형태

solid

반응 적합성

core: zinc
reagent type: catalyst

불순물

<0.2% water

density

1.84 g/mL at 25 °C (lit.)

SMILES string

CC(O[Zn]OC(C)=O)=O

InChI

1S/2C2H4O2.Zn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

DJWUNCQRNNEAKC-UHFFFAOYSA-L

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Zinc acetate is primarily utilized as a precursor or catalyst in various synthetic reactions. In organic chemistry, zinc acetate finds application as a reagent in the formation of carbon-carbon bonds. It can facilitate the synthesis of esters, allylic alcohols, and acetals. For example, it can promote the acylation of alcohols, phenols, and amines to form esters, such as the Fischer esterification reaction. Zinc acetate has also been used in the synthesis of metal-organic frameworks (MOFs). MOFs are porous materials consisting of metal ions or clusters coordinated to organic ligands. Zinc acetate can act as a precursor for the formation of MOFs due to its ability to coordinate with organic linkers and form robust networks.

For small scale and high throughput uses, product is also available as ChemBeads (927805)

애플리케이션

Zinc acetate has been used in:
  • Synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis.
  • Ultrasonic preparation of zinc sulfide nanoparticles coated on silica particles.
  • Synthesis of ZnO/ZnS composites throughion exchange method (1)
  • Fabrication of 3D hierarchical ZnO/ZnSheterojunction branched nanowires for enhanced photoelectrochemical watersplitting (2)
  • Synthesis of Co3O4-decorated ZnO@ZnS core-shellstructures for efficient photocatalytic overall water splitting (3)
  • Synthesis of ZnO photocatalysts (4)

제조 메모

Preparation of ZnSe nanostructures upon thermolysis of zinc acetate and selenourea in a mixture of octadecylamine and trioctylphosphine oxide.

픽토그램

CorrosionExclamation markEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

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문서 라이브러리 방문

Junsang Cho et al.
Langmuir : the ACS journal of surfaces and colloids, 33(15), 3711-3719 (2017-04-01)
Highly efficient blue-emitting CdSe-derived core/shell gradient alloy quantum dots (CSGA QDs) with photoluminescence quantum yield (PL QY) of ca. 90% have been synthesized through a facile "one-pot" approach. CdSe nuclei are initially formed as core and gradient alloy shells such
Abdelhay Aboulaich et al.
Inorganic chemistry, 49(23), 10940-10948 (2010-11-06)
Relatively monodisperse and highly luminescent Mn(2+)-doped zinc blende ZnSe nanocrystals were synthesized in aqueous solution at 100 °C using the nucleation-doping strategy. The effects of the experimental conditions and of the ligand on the synthesis of nanocrystals were investigated systematically.
Siu-Hong Chan et al.
PloS one, 5(2), e9071-e9071 (2010-02-09)
Helicobacter pylori is the etiologic agent of common gastritis and a risk factor for gastric cancer. It is also one of the richest sources of Type II restriction-modification (R-M) systems in microorganisms. We have cloned, expressed and purified a new
Asit Baran Panda et al.
Langmuir : the ACS journal of surfaces and colloids, 23(2), 765-770 (2007-01-11)
Shape-, size-, and phase-controlled ZnSe nanostructures were synthesized by thermolysis of zinc acetate and selenourea using liganding solvents of octadecylamine (ODA) and trioctylphosphineoxide (TOPO) at different molar ratios. Materials synthesized in pure ODA resulted in uniform ultranarrow nanorods and nanowires
Huiqing Wang et al.
Cellulose (London, England), 20(6), 3007-3024 (2013-01-01)
Photoluminiscent (PL) cellulose aerogels of variable shape containing homogeneously dispersed and surface-immobilized alloyed (ZnS)

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