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Merck
모든 사진(2)

Key Documents

359327

Sigma-Aldrich

N-Hexylmethylamine

96%

동의어(들):

N-Methylhexylamine

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About This Item

Linear Formula:
CH3NH(CH2)5CH3
CAS Number:
Molecular Weight:
115.22
Beilstein:
1731685
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

96%

형태

liquid

refractive index

n20/D 1.416 (lit.)

bp

140-142 °C (lit.)

density

0.76 g/mL at 25 °C (lit.)

작용기

amine

SMILES string

CCCCCCNC

InChI

1S/C7H17N/c1-3-4-5-6-7-8-2/h8H,3-7H2,1-2H3

InChI key

XJINZNWPEQMMBV-UHFFFAOYSA-N

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일반 설명

N-Hexylmethylamine is an acyclic secondary amine. Ruthenium-catalyzed reaction of N-hexylmethylamine with styrene has been reported. Transition metal-catalyzed intermolecular hydroamination of N-hexylmethylamine with 2-vinylnaphthalene has been reported.

애플리케이션

N-Hexylmethylamine may be used in the synthesis of dialkyldithiocarbamato cadmium complexes Cd[S2CNRR′]2.

픽토그램

FlameCorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

87.8 °F - closed cup

Flash Point (°C)

31 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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이미 열람한 고객

Masaru Utsunomiya et al.
Journal of the American Chemical Society, 126(9), 2702-2703 (2004-03-05)
A ruthenium-catalyzed intermolecular, anti-Markovnikov hydroamination of vinylarenes with secondary aliphatic and benzylic amines is reported. The combination of Ru(cod)(2-methylallyl)2, 1,5-bis(diphenylphosphino)pentane, and triflic acid was the most effective catalyst of those tested. Control reactions conducted without ligand or acid did not
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Chemistry of Materials, 14(7), 2900-2904 (2002)
Masaru Utsunomiya et al.
Journal of the American Chemical Society, 125(47), 14286-14287 (2003-11-20)
A transition metal-catalyzed intermolecular hydroamination of vinylarenes with alkylamines is reported. The combination of Pd(O2CCF3)4, DPPF, and TfOH was the most effective catalyst of those tested. Control experiments without palladium, acid, or ligand all occurred in low yield. The reaction

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