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Merck
모든 사진(3)

Key Documents

326712

Sigma-Aldrich

Ruthenium black

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동의어(들):

Ruthenium

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About This Item

실험식(Hill 표기법):
Ru
CAS Number:
Molecular Weight:
101.07
EC Number:
MDL number:
UNSPSC 코드:
12141739
PubChem Substance ID:
NACRES:
NA.23

분석

≥98%

Quality Level

형태

powder

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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저항도

7.1 μΩ-cm, 0°C

표면적

17-26 m2/g

bp

3900 °C (lit.)

mp

2310 °C (lit.)

density

12.45 g/cm3 (lit.)

환경친화적 대안 카테고리

SMILES string

[Ru]

InChI

1S/Ru

InChI key

KJTLSVCANCCWHF-UHFFFAOYSA-N

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애플리케이션

Ru based complexes may be used in the synthesis of anticancer drugs. Ru complexes in conjunction with magnesium may be used in the atom transfer radical addition (ATRA) and cyclization (ATRC) reactions.
Ru may be used as a catalyst in the following reactions;
  • oxidative coupling of indoles and pyrroles with several alkenes
  • arylations reactions.

포장

Packaged in glass bottles

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

nwg

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

이미 열람한 고객

Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.
Dipankar Srimani et al.
Angewandte Chemie (International ed. in English), 52(14), 4012-4015 (2013-03-08)
Bin Li et al.
The Journal of organic chemistry, 78(18), 9345-9353 (2013-09-13)
An efficient ruthenium-catalyzed oxidative coupling of indoles and pyrroles with various alkenes at the C2-position assisted by employing the N,N-dimethylcarbamoyl moiety as a directing group is reported. The catalytic reaction proceeds in an excellent regio- and stereoselective manner.
Lorraine Blackmore et al.
Chemical communications (Cambridge, England), 49(26), 2658-2660 (2013-02-26)
The targeted delivery of luminescent Ru(II) polypyridyl complexes to the nucleus of live mammalian cells by a Nuclear Localisation Signal (NLS) peptide; NF-κB is demonstrated.
M Beye et al.
Physical review letters, 110(18), 186101-186101 (2013-05-21)
We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et
Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and

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