317632

(Methylcyclopentadienyl)manganese(I) tricarbonyl

• 동의어(들): (Methylcyclopentadienyl)tricarbonylmanganese, MCMT, Tricarbonyl(2-methylcyclopentadienyl)manganese, Ethyl MMT, MMT, NSC 22316
• Linear Formula: C₅H₄CH₃Mn(CO)₃
• CAS Number: 12108-13-3
• Molecular Weight: 218.09
• EC Number: 235-166-5
• MDL number: MFCD00001426
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24859093
• NACRES: NA.22

속성

• vapor density: >1 (vs air)
• vapor pressure: 0.05 mmHg ( 20 °C)
• 양식: liquid
• 반응 적합성: core: manganese; reagent type: catalyst
• refractive index: n20/D 1.584 (lit.)
• bp: 232-233 °C (lit.)
• mp: −1 °C (lit.)
• density: 1.38 g/mL at 25 °C (lit.)
• SMILES string: [Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1
• InChI: 1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;
• InChI key: LYHJNAIHGFWRKM-UHFFFAOYSA-N

설명

일반 설명

Methylcyclopentadienyl manganese tricarbonyl (MMT) is commonly used as an antiknock agent in gasoline. It is also used as an additive in unleaded gasoline.

애플리케이션

Methylcyclopentadienyl manganese tricarbonyl can be used for doping of ZnSe nanocrystals.
It can also be used as a reactant for:

• Aldol addition reactions.
• Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units.
• Molecular fragmentation using shaped femtosecond laser pulses.
• Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE).

안전성 정보

• 픽토그램: GHS06,GHS08,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H301,H310 + H330,H315,H372,H410
• 예방조치 성명서: P262 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310 - P314
• Hazard Classifications: Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation
• 표적 기관: Lungs
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point (°F): 204.8 °F - closed cup
• Flash Point (°C): 96 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter