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Key Documents

267317

Sigma-Aldrich

Rhenium

foil, thickness 0.25 mm, 99.98% trace metals basis

동의어(들):

Rhenium element

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About This Item

실험식(Hill 표기법):
Re
CAS Number:
Molecular Weight:
186.21
MDL number:
UNSPSC 코드:
12141737
PubChem Substance ID:
NACRES:
NA.23

Quality Level

분석

99.98% trace metals basis

형태

foil

설명

19.3 μΩ-cm, 20°C

두께

0.25 mm

bp

5596 °C (lit.)
5627 °C (lit.)

mp

3180 °C (lit.)

density

21.02 g/cm3 (lit.)

SMILES string

[ReH]

InChI

1S/Re

InChI key

WUAPFZMCVAUBPE-UHFFFAOYSA-N

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일반 설명

Rhenium is a very hard, corrosion, and wear-resistant rare metal with ahigh atomic number. It is widely used in the field of catalysis and the preparationof alloys for jet engines.

애플리케이션

Rhenium can be used as a working electrode for electrochemical hydrogen evolution reactions.

It can be used as an additive to prepare a molybdenum-titanium-zirconium (TZM) alloy joint to improve its tensile strength.

It can also be used as a catalyst for various hydrodeoxygenation reactions.

수량

3.3 g = 25 × 25 mm; 13.2 g = 50 × 50 mm

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Titel Jurca et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4278-4286 (2013-02-02)
The development of rhenium(I) chemistry has been restricted by the limited structural and electronic variability of the common pseudo-octahedral products fac-[ReX(CO)3L2] (L2 = α-diimine). We address this constraint by first preparing the bidentate bis(imino)pyridine complexes [(2,6-{2,6-Me2C6H3N=CPh}2C5H3N)Re(CO)3X] (X = Cl 2
Ties J Korstanje et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(39), 13224-13234 (2013-08-16)
Rhenium-based complexes are powerful catalysts for the dehydration of various alcohols to the corresponding olefins. Here, we report on both experimental and theoretical (DFT) studies into the mechanism of the rhenium-catalyzed dehydration of alcohols to olefins in general, and the
Raphael Horvath et al.
Inorganic chemistry, 52(3), 1304-1317 (2013-01-15)
Transition-metal complexes of the types [Re(CO)(3)Cl(NN)], [Re(CO)(3)py(NN)](+), and [Cu(PPh(3))(2)(NN)](+), where NN = 4,4'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)-2,2'-bipyridine (OX) and 4,4'-bis(N,N-diphenyl-4-[ethen-1-yl]-aniline)-2,2'-bipyridine (DPA), have been synthesized and characterized. Crystal structures for [Re(CO)(3)Cl(DPA)] and [Cu(PPh(3))(2)(OX)]BF(4) are presented. The crystal structure of the rhenium complex shows a trans
Jonathan M Smieja et al.
Inorganic chemistry, 52(5), 2484-2491 (2013-02-20)
Electrocatalytic properties, X-ray crystallographic studies, and infrared spectroelectrochemistry (IR-SEC) of Mn(bpy-tBu)(CO)3Br and [Mn(bpy-tBu)(CO)3(MeCN)](OTf) are reported. Addition of Brönsted acids to CO2-saturated solutions of these Mn complexes and subsequent reduction of the complexes lead to the stable and efficient production of
Wilber Quispe-Tintaya et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(21), 8668-8673 (2013-04-24)
No significant improvement in therapy of pancreatic cancer has been reported over the last 25 y, underscoring the urgent need for new alternative therapies. Here, we coupled a radioisotope, (188)Rhenium, to an attenuated (at) live Listeria monocytogenes (Listeria(at)) using Listeria-binding

문서

Can there be an effective strategy for finding breakthrough materials, since they are, by definition, unpredictable? One answer is found in Combinatorial Materials Science techniques, which represent a powerful approach to identifying new and unexpected materials.

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