추천 제품
Quality Level
분석
98%
형태
liquid
refractive index
n20/D 1.396 (lit.)
bp
142-146 °C (lit.)
density
0.814 g/mL at 25 °C (lit.)
작용기
alkyl halide
fluoro
SMILES string
CCCCCCCCF
InChI
1S/C8H17F/c1-2-3-4-5-6-7-8-9/h2-8H2,1H3
InChI key
DHIVLKMGKIZOHF-UHFFFAOYSA-N
일반 설명
1-Fluorooctane undergoes C-F bond-cleavage reaction with phenyl magnesium chloride to give n-octylbenzene. It reacts rapidly with trimethylsilyl iodide to give corresponding octyl iodides and trimethylsilyl fluoride.
애플리케이션
1-Fluorooctane has been used as a molecular probe in evaluations of gas chromatographic stationary phases consisting of bromo- and chloro-derivatives of a C78 branched alkane.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
107.6 °F - closed cup
Flash Point (°C)
42 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Halogen redistribution reactions between alkyl halides and trimethylsilyl iodide.
Friedrich EC and De Lucca G.
Journal of Organometallic Chemistry, 226(2), 143-148 (1982)
Ervin Sz Kováts et al.
Journal of chromatography. A, 1113(1-2), 206-219 (2006-02-25)
In a paper published in 1992 [K.S. Reddy, J.-Cl. Dutoit, E.sz. Kováts, Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr. 609 (1992) 229] retention indices and standard chemical potential differences
Kouki Matsubara et al.
Organic letters, 11(8), 1765-1768 (2009-03-14)
An unexpected C-F bond-cleavage reaction of unactivated fluoroalkanes with the well-known Grignard reagents without using metal catalysts has been discovered. For example, a reaction between 1-fluorooctane and phenyl magnesium chloride gave n-octylbenzene in moderate yield. This coupling reaction via the
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