241512

Tetrabutylammonium fluoride hydrate

98%

• 동의어(들): TBAF
• Linear Formula: [CH₃(CH₂)₃]₄NF·xH₂O
• CAS Number: 22206-57-1
• Molecular Weight: 261.46 (anhydrous basis)
• MDL number: MFCD00149980
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24854487
• NACRES: NA.22

속성

• 분석: 98%
• 형태: solid
• mp: 62-63 °C (lit.)
• SMILES string: O.[F-].CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/C16H36N.FH.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;1H;1H2/q+1;;/p-1
• InChI key: UQCWXKSHRQJGPH-UHFFFAOYSA-M

설명

일반 설명

Tetrabutylammonium fluoride hydrate is known to be a source of F⁻ anion, used in nucleophilic fluorination reactions.

애플리케이션

Reactant for preparation of:

• Double clathrate hydrates at high pressures
• Cellulose ethers
• Terminal olefins via dehydrohalogenation reactions
• Neutral and zwitterionic 3-carboranyl thymidine analogues for boron neutron capture therapy

Tetrabutylammonium fluoride hydrate can be used:

• To prepare 2,7-diethynyl-9-propyl-9H-carbazole, which is a key intermediate for the synthesis of calix[4]arene−carbazole polymers.
• As an anion source in the study of selective detection of F⁻ by anion receptor viz Schiff base.
• To prepare terminal olefins from primary alkyl iodides

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314
• 예방조치 성명서: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges