238198

Dimethyl maleate

96%

• 동의어(들): (2Z)-2-Butenedioic acid dimethyl ester, (Z)-2-Butenedioic acid dimethyl ester, (Z)-Dimethyl 2-butenedioate, Dimethyl (Z)-but-2-enedioate
• Linear Formula: CH₃OCOCH=CHCOOCH₃
• CAS Number: 624-48-6
• Molecular Weight: 144.13
• Beilstein: 471705
• EC Number: 210-848-5
• MDL number: MFCD00008459
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24854145
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 96%
• 형태: liquid
• 불순물: ≤4% dimethyl fumarate
• refractive index: n20/D 1.441 (lit.)
• bp: 204-205 °C (lit.)
• solubility: water: soluble 77.9 g/L at 20 °C
• density: 1.152 g/mL at 25 °C (lit.)
• 작용기: ester
• SMILES string: [H]\C(=C(/[H])C(=O)OC)C(=O)OC
• InChI: 1S/C6H8O4/c1-9-5(7)3-4-6(8)10-2/h3-4H,1-2H3/b4-3-
• InChI key: LDCRTTXIJACKKU-ARJAWSKDSA-N

설명

일반 설명

Dimethyl maleate is a dienophile used as a chemical intermediate to synthesize dienes, plastics, and copolymers.

Dimethyl maleate (DMM) is a reactive dienophile and undergoes ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. Mesoporous siliceous SBA-15-supported Cu catalyzed gas phase hydrogenolysis of DMM to 1,4-butanediol (BDO) has been reported. Aluminium chloride has been reported to accelerate the Diels-Alder reaction of DMM and anthracene. DMM can be synthesized by the esterification of maleic anhydride with sulfuric acid and methanol.

애플리케이션

• Dissociation of bovine 6S procarboxypeptidase A by reversible condensation with 2,3-dimethyl maleic anhydride: application to the partial characterization of subunit III.: This study explores the dissociation of bovine procarboxypeptidase A using 2,3-dimethyl maleic anhydride, highlighting its applications in the partial characterization of enzyme subunits. The research demonstrates the potential of dimethyl maleate derivatives in protein chemistry and enzyme structure studies. (Puigserver and Desnuelle, 1975).

안전성 정보

• 픽토그램: GHS06,GHS08
• 신호어: Danger
• 유해 및 위험 성명서: H302,H311,H317,H319,H335,H373
• 예방조치 성명서: P260 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P314
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1 - STOT RE 2 Dermal - STOT SE 3
• 표적 기관: Respiratory system, Skin
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flash Point (°F): 203.0 °F - closed cup
• Flash Point (°C): 95 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter